📚 Mastering Calculation Questions from Complete Chemistry for Cambridge Secondary 1 Workbook | 掌握《完全剑桥初中化学1练习册》计算题型
The calculation questions in the Complete Chemistry for Cambridge Secondary 1 Workbook are designed to build your confidence in handling quantitative chemical problems. Mastering these skills – from relative atomic mass to concentration in g/dm³ – is essential for Cambridge Checkpoint Science and forms the backbone of IGCSE Chemistry.
《完全剑桥初中化学1练习册》中的计算题型旨在帮助你建立处理化学定量问题的信心。从相对原子质量到以 g/dm³ 为单位的浓度计算,掌握这些技能不仅是剑桥 Checkpoint 科学考试的关键,也为 IGCSE 化学打下坚实的基底。
1. Understanding Relative Atomic and Formula Mass | 理解相对原子质量与化学式量
Relative atomic mass (Aᵣ) is the average mass of an atom of an element compared to 1/12 the mass of a carbon-12 atom. It has no units. Relative formula mass (Mᵣ) is the sum of the Aᵣ values of all atoms in the chemical formula.
相对原子质量 (Aᵣ) 是元素一个原子的平均质量与碳-12原子质量的 1/12 比较得出的数值,无单位。化学式量 (Mᵣ) 是化学式中所有原子的 Aᵣ 值之和。
Example: Calculate Mᵣ of water (H₂O). Aᵣ of H = 1, O = 16. Mᵣ = (2 × 1) + 16 = 18.
示例:计算水 (H₂O) 的 Mᵣ。 Aᵣ(H) = 1,Aᵣ(O) = 16。 Mᵣ = (2 × 1) + 16 = 18。
| Element | Symbol | Aᵣ |
|---|---|---|
| Hydrogen | H | 1 |
| Carbon | C | 12 |
| Oxygen | O | 16 |
| Sodium | Na | 23 |
| Sulfur | S | 32 |
Common mistake: Forgetting to multiply the Aᵣ by the number of atoms shown in subscripts. In Ca(OH)₂, there are two OH groups, so O and H must each be counted twice.
常见错误:忘记将 Aᵣ 乘以下标所示的原子个数。在 Ca(OH)₂ 中,有两个 OH 基团,因此 O 和 H 各须计数两次。
2. Calculating Percentage Composition by Mass | 计算质量百分比组成
y mass of an element in a compound = (total mass of the element in the formula / Mᵣ) × 100%.
化合物中某元素的质量百分比 = (该元素在化学式中的总质量 / Mᵣ) × 100%。
ᵣ(N)=14, H=1, O=16. Mᵣ = (2×14) + (4×1) + (3×16) = 28+4+48=80. Mass of nitrogen = 2×14=28. %N = (28/80)×100% = 35%.
示例:求硝酸铵 NH₄NO₃ 中氮的质量百分比。Aᵣ(N)=14, H=1, O=16。 Mᵣ = (2×14)+(4×1)+(3×16)=28+4+48=80。氮的总质量 = 2×14=28。%N = (28/80)×100% = 35%。
Workbook questions often ask you to compare fertilisers by calculating the percentage of nutrient element they contain.
练习册中常要求通过计算营养元素的百分比来比较化肥。
3. Determining Empirical Formula from Mass Data | 从质量数据确定实验式
The empirical formula is the simplest whole-number ratio of atoms in a compound. It can be found from experimental mass or percentage data.
实验式(最简式)是化合物中原子最简整数比,可通过实验质量或质量百分比求得。
Steps: (1) Convert mass (or %) to moles by dividing by Aᵣ; (2) Divide all mole values by the smallest; (3) Multiply if necessary to get whole numbers.
步骤:(1) 用质量(或百分比)除以 Aᵣ 得到摩尔数;(2) 用最小值除所有摩尔值;(3) 必要时乘以整数得到最简单整数比。
A compound contains 40.0% carbon, 6.7% hydrogen and 53.3% .33, H=6.7/1=6.7, O=53.3/16=3.33. Divide by 3.33: C=1, H≈2, O=1. Empirical formula = CH₂O.
某化合物含碳 40.0%、氢 6.7%、氧 53.3%。假设 100 g 样品:C 的摩尔数 40.0/12=3.33,H 6.7/1=6.7,O 53.3/16=3.33。均除以 3.33 得 C=1, H≈2, O=1。实验式为 CH₂O。
Note: If you are given the relative molecular mass, you can then find the molecular formula by comparing Mᵣ with empirical formula mass.
注意:若已知相对分子质量,便可比较 Mᵣ 与实验式量,求出分子式。
4. Reacting Mass Calculations Using Chemical Equations | 利用化学方程式计算反应质量
Chemical equations tell us the ratio in which moles react. We use the balanced equation and Mᵣ values to calculate reacting masses directly.
化学方程式揭示物质反应的摩尔比。我们依据配平的方程式和 Mᵣ 值直接计算反应质量。
O₂ → 2MgO. How many grams of magnesium oxide form when 12 g of magnesium burns completely? n, 2 mol Mg (2×24=48 g) produce 2 mol MgO (2×40=80 g). So 12 g Mg → (12/48)×80 = 20 g MgO.
示例:2Mg + O₂ → 2MgO。 12 g 镁完全燃烧生成多少克氧化镁? Aᵣ(Mg)=24, O=16,Mᵣ(MgO)=40。 根据方程式,2 mol Mg (48 g) 生成 2 mol MgO (80 g)。 故 12 g Mg 生成 (12/48)×80 = 20 g MgO。
Mass product = (given mass reactant / Mᵣ reactant scaled) × Mᵣ product scaled
生成物质量 = (给定反应物质量 / 反应物的缩放质量) × 生成物的缩放质量
Always check that the equation is balanced before you start.
计算前务必确认方程式已配平。
5. Identifying the Limiting Reactant | 识别限量反应物
When two reactants are given, one will often be used up first – the limiting reactant – and it determines the amount of product formed.
当提供两种反应物的质量时,其中一种常会先消耗完——即限量反应物——它决定了产物的生成量。
1 mol O₂, so both are exactly used. If we had 4 g H₂ and 16 g O₂, O₂ = 0.5 mol, H₂ = 2 mol; O₂ is limiting. Water produced = 2×0.5=1 mol = 18 g.
示例:4 g H₂ 与 32 g O₂ 反应生成水。 2H₂ + O₂ → 2H₂O。 H₂ 的摩尔数 = 4/2=2 mol, O₂ 的摩尔数 = 32/32=1 mol。 方程式要求 2 mol H₂ 与 1 mol O₂ 恰好完全反应。 若是 4 g H₂ 与 16 g O₂,O₂=0.5 mol, H₂=2 mol,O₂ 是限量反应物,生成水 2×0.5=1 mol,即 18 g。
The limiting reactant can be identified by converting both given masses to moles, then comparing to the mole ratio from the equation.
辨别限量反应物的方法是:将两种物质的质量换算为摩尔数,再与方程式中的摩尔比进行比较。
6. Concentration Calculations in g/dm³ | 以 g/dm³ 为单位的浓度计算
ation (g/dm³) = mass of solute (g) / volume of solution (dm³). Remember: 1 dm³ = 1000 cm³.
浓度 (g/dm³) = 溶质质量 (g) / 溶液体积 (dm³)。 注意:1 dm³ = 1000 cm³。
e 200 cm³ of solution. Volume in dm³ = 200/1000=0.2 dm³. Concentration = 5/0.2 = 25 g/dm³.
示例:将 5 g 食盐溶于水配成 200 cm³ 溶液。体积 = 200/1000=0.2 dm³。 浓度 = 5/0.2 = 25 g/dm³。
Many workbook errors come from forgetting to convert cm³ to dm³. Always check the units given in the question.
练习册中的许多错误都源于忘记将 cm³ 换算为 dm³。 务必检查题目中的单位。
c (g/dm³) = m (g) / V (dm³)
浓度 c (g/dm³) = 溶质质量 m (g) / 溶液体积 V (dm³)
7. Making Solutions and Dilution Calculations | 配制溶液与稀释计算
n of a desired concentration, the mass of solute needed = concentration × volume (in dm³).
配制指定浓度的溶液时,所需溶质质量 = 浓度 × 体积 (dm³)。
Example: How many grams of sugar are needed to make 250 cm
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